A Review of Group 2 (Ca, Sr, Ba) Metal-Organic Compounds as Precursors for Chemical Vapor Deposition

Atomic Layer Deposition of SrTiO3 Thin Films from a Novel Strontium Precursor-Strontium-bis(tri-isopropyl cyclopentadienyl)

“…[36] In general, cyclopentadienyls of strontium and barium have been considered too air and moisture sensitive to be useful in CVD and thus their use has been only briefly reported. [8,16,37] Our experiments showed that, with careful handling, they may be used without difficulty in ALD. In this work, we have performed a detailed study on the ALD growth of SrTiO 3 by using strontium bis(tri-isopropylcyclopentadienyl) (Sr(C 5 i Pr 3 H 2 ) 2 ) as the novel strontium precursor, and…”

Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations Mg(II), Ca(II), Ba(II) and Sr(II): synthesis and characterization

“…Some complex structures stated have thermochromic, solvatochromic and ionochromic properties depending on deaquation [12]. Also, the alkaline earth metal cation complexes with organic ligands were studied and investigated their bonding parameters by lots of researcher [13][14][15][16][17][18] The importance of studies related with transition metal complexes of nicotinamide acting as vitamin B 3 and used in drug preparation has been increased recently. As a result of spectral investigation of complexes between nicotinamide and these metals, it was determined that it has ability to bind as monodentate ligand through pyridine nitrogen.…”

Synthesis and characterization of cyclopentadienylgallium amide compounds as potential single source precursors to GaN

“…Most commonly these ligands are associated with transition metals; however, cyclopentadienyl compounds of main group metal and metalloid elements have also received considerable attention for their diverse and unusual structures and their fluxional behavior [1][2][3][4][5]. These compounds are also of interest as potential precursors in metal-organic chemical vapor deposition (MOCVD) [3], as ligands for transition metals [4], as synthetic precursors to organometallic complexes [5], in catalysis [6], and as molecular precursors to materials [7].…”