Besides aliphatic gasoline, ethanol-blended gasoline
intended for use in small utility engines was recently
introduced on the Swedish market. For small utility engines,
little data is available showing the effects of these fuels
on exhaust emissions, especially concerning aldehydes and
ketones (carbonyls). The objective of the present
investigation was to study carbonyl emissions and
regulated emissions from a two-stroke chain saw engine
using ethanol, gasoline, and ethanol-blended gasoline as fuel
(0%, 15%, 50%, 85%, and 100% ethanol). The effects of
the ethanol-blending level and mechanical changes of the
relative air/fuel ratio, λ, on exhaust emissions was
investigated, both for aliphatic and regular gasoline.
Formaldehyde, acetaldehyde, and aromatic aldehydes
were the most abundant carbonyls in the exhaust.
Acetaldehyde dominated for all ethanol-blended fuels (1.2−12 g/kWh, depending on the fuel and λ), and formaldehyde
dominated for gasoline (0.74−2.3 g/kWh, depending on
the type of gasoline and λ). The main effects of ethanol
blending were increased acetaldehyde emissions (30−44
times for pure ethanol), reduced emissions of all other
carbonyls except formaldehyde and acrolein (which showed
a more complex relation to the ethanol content), reduced
carbon monoxide (CO) and ntirogen oxide (NO) emissions,
and increased hydrocarbon (HC) and nitrogen dixodie (NO2)
emissions. The main effects of increasing λ were increased
emissions of carbonyls and nitrogen oxides (NO
x
) and
reduced CO and HC emissions. When the two types of
gasoline are considered, benzaldehyde and tolualdehyde
could be directly related to the gasoline content of aromatics
or olefins, but also acrolein, propanal, crotonaldehyde,
and methyl ethyl ketone mainly originated from aromatics
or olefins, while the main source for formaldehyde,
acetaldehyde, acetone, methacrolein, and butanal was
saturated aliphatic hydrocarbons.