A review of the toxicology presence and removal of ketoprofen through adsorption technology

Georgin, Jordana; Franco, Dison S.P.; Martinello, Kátia da Boit; Lima, Éder C.; Silva, Luis

doi:10.1016/j.jece.2022.107798

Cited by 54 publications

(13 citation statements)

References 121 publications

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“…The application of adsorption processes, including biosorption, has shown a high potential for the eliminations of pharmaceuticals ( Georgin et al, 2022 ). Although the use of algae for the removal of NSAIDs is a relatively new area of research, several studies have reported their effectiveness in addressing pharmaceutical contamination.…”

Section: Bioremoval Of Ketoprofenmentioning

confidence: 99%

Ketoprofen as an emerging contaminant: occurrence, ecotoxicity and (bio)removal

Tyumina,

Subbotina,

Polygalov

et al. 2023

Front. Microbiol.

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Ketoprofen, a bicyclic non-steroidal anti-inflammatory drug commonly used in human and veterinary medicine, has recently been cited as an environmental contaminant that raises concerns for ecological well-being. It poses a growing threat due to its racemic mixture, enantiomers, and transformation products, which have ecotoxicological effects on various organisms, including invertebrates, vertebrates, plants, and microorganisms. Furthermore, ketoprofen is bioaccumulated and biomagnified throughout the food chain, threatening the ecosystem function. Surprisingly, despite these concerns, ketoprofen is not currently considered a priority substance. While targeted eco-pharmacovigilance for ketoprofen has been proposed, data on ketoprofen as a pharmaceutical contaminant are limited and incomplete. This review aims to provide a comprehensive summary of the most recent findings (from 2017 to March 2023) regarding the global distribution of ketoprofen in the environment, its ecotoxicity towards aquatic animals and plants, and available removal methods. Special emphasis is placed on understanding how ketoprofen affects microorganisms that play a pivotal role in Earth’s ecosystems. The review broadly covers various approaches to ketoprofen biodegradation, including whole-cell fungal and bacterial systems as well as enzyme biocatalysts. Additionally, it explores the potential of adsorption by algae and phytoremediation for removing ketoprofen. This review will be of interest to a wide range of readers, including ecologists, microbiologists, policymakers, and those concerned about pharmaceutical pollution.

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Section: Bioremoval Of Ketoprofenmentioning

confidence: 99%

Ketoprofen as an emerging contaminant: occurrence, ecotoxicity and (bio)removal

Tyumina,

Subbotina,

Polygalov

et al. 2023

Front. Microbiol.

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“…Numerous methods have been investigated as a result of this issue, mostly for the removal and degradation of this chemical [ 1 , 16 , 17 , 18 , 19 ], for example, photolysis, photo-Fenton, photocatalysis, ozonation, nanofiltration, and adsorption [ 18 , 19 , 20 ]. Adsorption is a popular method for eliminating contaminants from water and wastewater due to its effectiveness and low cost [ 21 , 22 , 23 , 24 ]. Adsorption has the advantage of being able to use new adsorbents produced from plant leftovers [ 25 , 26 ].…”

Section: Introductionmentioning

confidence: 99%

The Synthesis and Evaluation of Porous Carbon Material from Corozo Fruit (Bactris guineensis) for Efficient Propranolol Hydrochloride Adsorption

Franco,

Georgin,

Ramos

et al. 2023

Molecules

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This study explores the potential of the corozo fruit (Bactris guineensis) palm tree in the Colombian Caribbean as a source for porous carbon material. Its specific surface area, pore volume, and average pore size were obtained using N2 adsorption/desorption isotherms. The images of the precursor and adsorbent surface were obtained using scanning electron microscopy (SEM). Fourier transform infrared (FTIR) spectra were obtained to detect the main functional groups present and an X-ray diffraction analysis (XRD) was performed in order to analyze the structural organization of the materials. By carbonizing the fruit stone with zinc chloride, a porous carbon material was achieved with a substantial specific surface area (1125 m2 g⁻1) and pore volume (3.241 × 10−1 cm3 g⁻1). The material was tested for its adsorption capabilities of the drug propranolol. The optimal adsorption occurred under basic conditions and at a dosage of 0.7 g L⁻1. The Langmuir homogeneous surface model effectively described the equilibrium data and, as the temperature increased, the adsorption capacity improved, reaching a maximum of 134.7 mg g⁻1 at 328.15 K. The model constant was favorable to the temperature increase, increasing from 1.556 × 10−1 to 2.299 × 10−1 L mg−1. Thermodynamically, the adsorption of propranolol was found to be spontaneous and benefited from higher temperatures, indicating an endothermic nature (12.39 kJ mol⁻1). The negative ΔG0 values decreased from −26.28 to −29.99 kJ mol−1, with the more negative value occurring at 328 K. The adsorbent material exhibited rapid kinetics, with equilibrium times ranging from 30 to 120 min, depending on the initial concentration. The kinetics data were well-represented by the general order and linear driving force models. The rate constant of the general order model diminished from 1.124 × 10−3 to 9.458 × 10−14 with an increasing concentration. In summary, the leftover stone from the Bactris guineensis plant can be utilized to develop activated carbon, particularly when activated using zinc chloride. This material shows promise for efficiently adsorbing propranolol and potentially other emerging pollutants.

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Section: Introductionmentioning

confidence: 99%

“…[25] Adsorption has been regarded as one of the most effective methods for removing dyes because of its straightforward design, high efficacy, ease of handling, and low cost. [26][27][28][29] In the literature, it is possible to find several studies that synthesize adsorbents from residues for dye removal, such as phaseolus vulgaris L. for the removal of reactive red 198 dye, [30] coir pith, sawdust, and sugarcane fibre for the removal of crystal violet and rhodamine B, [31] sesame hull (Sesamum indicum L.) for the removal of methylene blue (MB), [32] soybean hull for the removal of safranin dye, [33] Musa acuminata and Solanum tuberosum peels for emerald green dye removal, [34] Bengal gram bean husk for removing MB and methylene orange (MO), [35] Citrullus Lanatus peels for removing acidic dyes, [36] pecan pericarp (Carya illinoensis) for removing methyl violet 2B, [37] and a pod of forest species [38,39] and tree bark [40,41] in the removal of cationic dyes, among others.…”

mentioning

confidence: 99%

Transformation of Mytella falcata residual shell into CaAl/LDH adsorbent: Removal of methyl orange and methylene blue dyes

Henrique

Duarte

et al. 2023

Can J Chem Eng

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This study analyzed the viability of using malacoculture residue (Mytella falcata) to produce layered double hydroxides (LDHs) and for its subsequent use as an adsorbent. The CaAl/LDH‐RE material was produced with calcium oxide from the residue and the CaAl/LDH‐AP was produced with a commercial reagent. Both were used to remove methyl orange (MO) and methylene blue (MB) dyes. The CaAl/LDH‐RE presented a surface area of 28.54 m2 g−1, being 65.62% larger than the CaAl/LDH‐AP material (17.23 m2 g−1). The adsorbents showed mesopores distributed on a surface formed by plates in the form of hexagonal sheets arranged in an overlapping manner. The dosage of 0.05 g L−1 obtained the removal of 95% and 97% for MO, while for MB it was 94% and 93% using the adsorbents LDH/CaAl‐AP and LDH/CaAl‐RE, respectively. The system reached equilibrium at 90 min for MO and 120 min for MB. The pseudo‐second order model well represented the kinetic data reaching 11.36 mg g−1 (CaAl/LDH‐RE) and 8.42 mg g−1 (CaAl/LDH‐AP) for MO, and 4.47 mg g−1 (CaAl/LDH‐RE) and 4.14 mg g−1 (CaAl/LDH‐AP) for MB. The Freundlich model better represented the isothermal data, where the temperature exerted little influence. Adsorbents showed similar removal percentages in real and synthetic matrices. The LDH/CaAl‐RE can be applied in up to 3 cycles, maintaining its adsorption capacity. These results corroborate the use of MFW to produce CaAl/LDH‐RE, which can be used for the efficient removal of organic pollutants in an aqueous solution.

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A review of the toxicology presence and removal of ketoprofen through adsorption technology

Cited by 54 publications

References 121 publications

Ketoprofen as an emerging contaminant: occurrence, ecotoxicity and (bio)removal

Ketoprofen as an emerging contaminant: occurrence, ecotoxicity and (bio)removal

The Synthesis and Evaluation of Porous Carbon Material from Corozo Fruit (Bactris guineensis) for Efficient Propranolol Hydrochloride Adsorption

Transformation of Mytella falcata residual shell into CaAl/LDH adsorbent: Removal of methyl orange and methylene blue dyes

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