This study provides
an efficient and straightforward approach to
eliminate carbon dioxide (CO2) by absorption using a calcium
oxide (CaO) sorbent derived from chicken eggshells. The sorbent concentration,
stirring speed, and contact time were varied. The optimal condition
for CO2 removal was a 10% calcium hydroxide (Ca(OH)2) suspension at 600 rpm with 20 min interaction. This optimum
condition conferred the ever-highest absorption (98.71%) of CO2 through Ca(OH)2 suspensions from eggshell-derived
CaO. X-ray diffraction was used to identify crystallographic phases
and optimum conditions revealed calcium carbonate (CaCO3) formation with the highest intensity, Fourier transform infrared
spectroscopy revealed peaks for the carbonate (CO3
2–) group, field emission scanning electron microscopy
was used to investigate the morphological and structural properties
of the sorbent before and after CO2 absorption, and thermogravimetric
analysis was performed to understand the reaction mechanism. According
to the kinetic analysis, the sorbent can be fully decomposed with
a minimum activation energy (E
a) of 89.09
kJ/mol.