A review on designing and synthesis of lanthanide based macrocyclic complexes and their potential applications

Atal, Krishna; Phageria, Urmila; Kumari, Sushama; Dhayal, Yogpal; Bugalia, Swati

doi:10.1016/j.ica.2023.121857

Inorganica Chimica Acta

2024

DOI: 10.1016/j.ica.2023.121857

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A review on designing and synthesis of lanthanide based macrocyclic complexes and their potential applications

Krishna Atal,

Urmila Phageria,

Sushama Kumari

et al.

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2024

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Cited by 2 publications

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N-(1H-Benzo[d]imidazol-2-yl)-1-(3-substituted phenyl) methanimines as optoelectronic and nonlinear optical materials: spectroscopic and computational approaches

Ojo,

Adekusibe,

Odozi

et al. 2024

Chem. Pap.

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N-(1H-Benzo[d]imidazol-2-yl)-1-(3-substituted phenyl) methanimines as optoelectronic and nonlinear optical materials: spectroscopic and computational approaches

Ojo,

Adekusibe,

Odozi

et al. 2024

Chem. Pap.

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A Novel Mn-Based Film with Oxygen Vacancy for Efficient and Selective K⁺ Separation

Li,

Wang,

Zhang

et al. 2024

Ind. Eng. Chem. Res.

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In this study, a novel electrical Mn-based film was developed for selective potassium (K + ) separation, in which delaminated MnO x was obtained with the assistance of Ho 3+ using a facile coprecipitation method and coated on carbon paper with poly(vinylidene fluoride) (PVDF) and graphitized carbon black. With the scanning electron microscope (SEM) and transmission electron microscope (TEM) observations, it was found that abundant multiphase interfaces and lattice dislocations appeared on the bulk of Ho-MnO x . Brunauer−Emmett−Teller (BET) analysis verified that the delamination assisted by Ho 3+ increased the specific surface area from 110.3 m 2 /g (MnO x ) to 166.8 m 2 /g (1% Ho-MnO x ), which should be beneficial for the exposing of more electrochemical active areas and active sites for K + adsorption and separation. Particularly, 1% Ho-MnO x had a high concentration of oxygen vacancies and showed a better K + adsorption ability than MnO x . It was considered that the adsorption of K + was mainly affected by the ion memory toward K + for the 1% Ho-MnO x . In addition, the 1% Ho-MnO x film had good stable retention and regeneration capability for the separation of K + ; after 10 cycles of adsorption and desorption, the film still retained 87.24% of the maximum adsorption capacity for K + . It is expected to provide an effective preparation method to obtain a high-performance K + removal film electrode for the separation of K + under a low concentration.

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A review on designing and synthesis of lanthanide based macrocyclic complexes and their potential applications

Cited by 2 publications

References 109 publications

N-(1H-Benzo[d]imidazol-2-yl)-1-(3-substituted phenyl) methanimines as optoelectronic and nonlinear optical materials: spectroscopic and computational approaches

N-(1H-Benzo[d]imidazol-2-yl)-1-(3-substituted phenyl) methanimines as optoelectronic and nonlinear optical materials: spectroscopic and computational approaches

A Novel Mn-Based Film with Oxygen Vacancy for Efficient and Selective K⁺ Separation

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A review on designing and synthesis of lanthanide based macrocyclic complexes and their potential applications

Cited by 2 publications

References 109 publications

N-(1H-Benzo[d]imidazol-2-yl)-1-(3-substituted phenyl) methanimines as optoelectronic and nonlinear optical materials: spectroscopic and computational approaches

N-(1H-Benzo[d]imidazol-2-yl)-1-(3-substituted phenyl) methanimines as optoelectronic and nonlinear optical materials: spectroscopic and computational approaches

A Novel Mn-Based Film with Oxygen Vacancy for Efficient and Selective K+ Separation

Contact Info

Product

Resources

About

A Novel Mn-Based Film with Oxygen Vacancy for Efficient and Selective K⁺ Separation