A review on diverse applications of electrochemically active functional metallopolymers

An Encyclopedic Compendium on Chemosensing Supramolecular Metal‐Organic Gels

“…[75] Zhang et al recently reviewed materials developed from MOGs themselves for their electrochemical purposes. [20] Apart from this, a review of diverse applications of electrochemically active functional metallopolymers [265] is also available. A straightforward method to attain a metastable metal oxide brought in carbonized metal-organic gels is reported.…”

Effect of a single methyl substituent on the electronic structure of cobaltocene studied by computationally assisted MATI spectroscopy

“…Since discovery of the intriguing sandwich structure of (Cp) 2 Fe seven decades ago 1,2 metallocenes have become one of the most prominent classes of organometallics. During last years, cobaltocene and its substituted derivatives have been attracting special interest due to their relevance to modern catalytic systems, [3][4][5] sensors, [6][7][8] metallopolymers, [9][10][11][12] and molecular magnets, 13 as well as to the materials for hydrogen evolution, [14][15][16] batteries, [17][18][19][20][21][22] solar cells [23][24][25] and spintronics. 13,26,27 The adiabatic ionization energy I ad.…”

“…[33][34][35][36][37][38] The ability of the (Cp) 2 Co molecule to form easily a stable cobaltocenium cation appears to be crucial for its practical use, e.g. in redox polymers 10,11,39,40 or bioelectrocatalysis. 39,41 That is why detailed information on the changes in the molecular and electronic structure accompanying ionization of (Cp) 2 Co is of key importance for understanding its behavior in various chemical processes.…”