A review on electrospun polyvinylpyrrolidone-derived carbon composite nanofibers as advanced functional materials for energy storage applications and beyond

Belgibayeva, Ayaulym; Berikbaikyzy, Samal; Sagynbay, Yrysgul; Turarova, Gulderaiym; Taniguchi, Izumi; Bakenov, Zhumabay

doi:10.1039/d3ta01198d

Cited by 15 publications

(6 citation statements)

References 158 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The term "responsive factor" typically refers to specific sensitive substances that undergo changes in response to external stimuli. For instance, photoresponsive materials commonly include polyvinylpyrrolidone [72,73] and TiO 2 , [74,75] electric-responsive materials encompass graphene, [76,77] carbon nanotubes, [78,79] and metal oxides, [80,81] while magnetic-responsive materials comprise Fe, Co, Ni, [82] as well as iron oxides (Fe 3 O 4 , [83,84] γ-Fe 2 O 3 [85,86] ), among others. Noteworthy external environmental stimuli include light, electricity, and magnetism.…”

Section: Smart Responsive Superhydrophobic Mechanismmentioning

confidence: 99%

Advances in the Research of Photo, Electrical, and Magnetic Responsive Smart Superhydrophobic Materials: Synthesis and Potential Applications

Wang,

Qu,

Ren

et al. 2023

Chemistry An Asian Journal

View full text Add to dashboard Cite

With the rapid advancement of technology, the wettability of conventional superhydrophobic materials no longer suffice to meet the demands of practical applications. Intelligent responsive superhydrophobic materials have emerged as a highly sought‐after material in various fields. The exceptional superhydrophobicity, reversible wetting, and intelligently controllable characteristics of these materials have led to extensive applications across industries, including industry, agriculture, defense, and medicine. Therefore, the development of intelligent superhydrophobic materials with superior performance, economic practicality, enhanced sensitivity, and controllability assumes utmost importance in advancing technology worldwide. This article provides a summary of the wettability principles of superhydrophobic surfaces and the mechanisms behind intelligent responsive superhydrophobicity. Furthermore, it reviews and analyzes the recent research progress on light, electric, and magnetic responsive superhydrophobic materials, encompassing aspects such as material synthesis, modification, performance, and responses under diverse external stimuli. The article also explores the challenges associated with different types of responsive superhydrophobic materials and the unique application prospects of light, electric, and magnetic responsive superhydrophobic materials. Additionally, it outlines the future directions for the development of intelligent responsive superhydrophobic materials.

show abstract

Section: Smart Responsive Superhydrophobic Mechanismmentioning

confidence: 99%

Advances in the Research of Photo, Electrical, and Magnetic Responsive Smart Superhydrophobic Materials: Synthesis and Potential Applications

Wang,

Qu,

Ren

et al. 2023

Chemistry An Asian Journal

View full text Add to dashboard Cite

show abstract

“…The formation of the finer nanoparticles with an increase of the H 3 PO 4 content could be attributed to the formation of a strong phosphate carcass that interacted with functional groups of PVP and formed isolated nucleation sites for the restricted growth of particles. [27,28] Lack of phosphate anions in the precursor structure, on the other hand, allows free diffusion of ions, growth of bigger particles, and phosphorus evaporation.…”

Section: Synthesis Of Free-standing Tin Phosphide/phosphate Carbon Co...mentioning

confidence: 99%

Synthesis of Free‐Standing Tin Phosphide/Phosphate Carbon Composite Nanofibers as Anodes for Lithium‐Ion Batteries with Improved Low‐Temperature Performance

Belgibayeva

Rakhatkyzy

Rakhmetova

et al. 2023

Small

Self Cite

View full text Add to dashboard Cite

Free‐standing tin phosphide/phosphate carbon composite nanofiber mats of unique nanostructure have been successfully synthesized by electrospinning and partially reducing the phosphate‐containing precursors. An unusual effect of the Sn:P molar ratio in the precursor solution on the structure and physical‐electrochemical properties of the material is observed. Physical characterizations, including X‐Ray diffraction (XRD), Raman spectroscopy, X‐Ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM), confirm the formation of tin phosphide/phosphate nanoparticles of P‐rich inner SnxP layer and Sn‐rich outer layer uniformly distributed within carbon nanofiber matrix when the Sn:P=1:1. The prepared material is tested as an anode material for lithium‐ion batteries and it retains 1141 mAh g−1 charge capacity after 300 cycles at a current density of 250 mA g−1 with almost 100% Coulombic efficiency at room temperature. Furthermore, it demonstrates six times higher capacity (846 mAh g−1) at 0 °C compared to a commercial graphite anode and stable cyclability at −20 °C and 50 mA g−1. Post‐mortem ex situ XRD and SEM analyses confirm the structural stability of the designed material and the formation of a uniform stable solid electrolyte interphase layer even after 100 cycles at 50 mA g−1.

show abstract

“…Electrospinning represents a straightforward, cost-effective, and easily controllable method for fabricating one-dimensional nanomaterials. During electrospinning, electrostatic forces overcome the surface tension of the precursor solution, allowing the solvent jetting stream to evaporate in the air and form nanofibers. ,− Utilizing coaxial electrospinning, this technique employs nozzles with core and shell layers, enabling the formation of nanofibers with corresponding layered structures through the spraying of jets . 1,4,5,8-Naphthalene tetracarboxylic acid (NTCA) and 3,3′-diaminobenzidine (DAB) combine to form poly(NTCA/DAB) supramolecules (PNDS) in a N,N-dimethylformamide (DMF) solution of polyvinylpyrrolidone (PVP), with PVP serving as a template for the reaction .…”

Section: Introductionmentioning

confidence: 99%

Electrospun Core–Shell Carbon Nanofibers as Free-Standing Anode Materials for Sodium-Ion Batteries

Li,

Pei,

et al. 2024

ACS Appl. Nano Mater.

View full text Add to dashboard Cite

The development of wearable devices requires flexible batteries that can be bent and folded. However, deficiencies in material flexibility, conductivity, and other aspects can affect the performance of a flexible electrode. One-dimensional nanofibers possess high specific surface area, high conductivity, and a 3D network structure that enables them to buffer stress and strain. Consequently, they hold significant potential in the field of electrochemical energy storage as flexible electrode materials. In this study, we utilized polyvinylpyrrolidone (PVP) as a template to form a supramolecular polymer (PNDS) through hydrogen bonding between 1,4,5,8-naphthalene tetracarboxylic acid (NTCA) and 3,3′-diaminobenzidine (DAB) monomers. Through core−shell electrospinning and carbonization, PNDS precursors were used to prepare polybis(benzimidazobenzophenanthroline-dione) (BBB)-based carbon nanofibers featuring a core−shell structure. The BBB polymer, featuring a continuous aromatic ring structure, undergoes conversion into a highly graphitic carbon skeleton upon carbonization at 1000 °C. This transformation enhances the conductivity of flexible electrodes, improves the current collection effect under high currents, and ensures stability in the charge−discharge cycle. The iron-containing polymers within the shell layer ultimately transform into iron oxide and iron carbide nanoparticles encapsulated within the carbon fibers, compensating for the lower specific capacity characteristic of pure carbon materials. Serving as a SIB flexible anode, the specific capacity can achieve 250 mAh g −1 after 950 cycles at 0.2 A g −1 , with negligible attenuation throughout the cycling process. This study demonstrates that BBB-based carbon nanofibers featuring core−shell structures exhibit excellent electrochemical performance while retaining flexibility, presenting clear advantages over traditional electrodes characterized by complicated processes and limited active substance content.

show abstract

A review on electrospun polyvinylpyrrolidone-derived carbon composite nanofibers as advanced functional materials for energy storage applications and beyond

Abstract: The growing energy demand leads to the excessive combustion of fossil fuels and contributes to CO2-induced global warming. On the other hand, new sustainable energy solutions require the development of...

Cited by 15 publications

References 158 publications

Advances in the Research of Photo, Electrical, and Magnetic Responsive Smart Superhydrophobic Materials: Synthesis and Potential Applications

Advances in the Research of Photo, Electrical, and Magnetic Responsive Smart Superhydrophobic Materials: Synthesis and Potential Applications

Synthesis of Free‐Standing Tin Phosphide/Phosphate Carbon Composite Nanofibers as Anodes for Lithium‐Ion Batteries with Improved Low‐Temperature Performance

Electrospun Core–Shell Carbon Nanofibers as Free-Standing Anode Materials for Sodium-Ion Batteries

Contact Info

Product

Resources

About