To solve the problem of heat resistance of the oil film in the evaporator
pipeline of the ammonia refrigeration system, it is extremely important to
study the interaction mechanism of the oil/ammonia system. The method of
dissipative molecular dynamics is used to simulate the oil/ammonia flow
state at different temperatures and concentrations, and the mechanism of its
interaction was analyzed. It was also found that various parameters are
greatly affected by temperature in the research process, the linear
relationship of temperature on various parameters was quantitatively
calculated. The oil/ammonia system were divided into emulsion and layered
liquid. The oil phase (or ammonia phase) with low percentage at low
temperature all exists in the form of droplets. The oil-ammonia interfacial
tension first increases and then decreases with the increase of oil content.
At the same temperature, the interfacial tension reached its maximum when
the oil content was 70%. The oil percentage of 30% concentration was the
phase inversion point. When the oil percentage was 30-70%, the oil and
ammonia two phases were stratified, and the oil adhered to the surface of
the pipe wall. Therefore, the heat transfer performance of the system was
the worst when the oil content was 30-70%. As the temperature increased, the
interaction parameter aij decreased significantly. The linear relationship
between ? and 1/T was very consistent with the Flory-Huggins mean field
theory. This linear equation provided a basis for subsequent related
research.