A review on gold–ammonia bonding patterns

Kryachko, Eugene S.; Remacle, Françoise

doi:10.1007/978-1-4020-5460-0_7

Cited by 3 publications

(1 citation statement)

References 41 publications

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“…H bonding of the auride anion (Au – ···HX) has been studied extensively with both theory and experiments. Many of the earlier studies included computational and gas-phase studies evaluating the H bonding between Au – and prototypical H bond donors, such as (H 2 O) n , − (NH 3 ) n , , and (HF) n . In these complexes, it was found that Au – could sustain moderate to strong H bonding.…”

Section: Introductionmentioning

confidence: 99%

Comparison of Conventional and Nonconventional Hydrogen Bond Donors in Au^– Complexes

et al. 2022

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Although gold has become a well-known nonconventional hydrogen bond acceptor, interactions with nonconventional hydrogen bond donors have been largely overlooked. In order to provide a better understanding of these interactions, two conventional hydrogen bonding molecules (3-hydroxytetrahydrofuran and alaninol) and two nonconventional hydrogen bonding molecules (fenchone and menthone) were selected to form gas-phase complexes with Au – . The Au – [M] complexes were investigated using anion photoelectron spectroscopy and density functional theory. Au – [fenchone], Au – [menthone], Au – [3-hydroxyTHF], and Au – [alaninol] were found to have vertical detachment energies of 2.71 ± 0.05, 2.76 ± 0.05, 3.01 ± 0.03, and 3.02 ± 0.03 eV, respectively, which agree well with theory. The photoelectron spectra of the complexes resemble the spectrum of Au – but are blueshifted due to the electron transfer from Au – to M. With density functional theory, natural bond orbital analysis, and atoms-in-molecules analysis, we were able to extend our comparison of conventional and nonconventional hydrogen bonding to include geometric and electronic similarities. In Au – [3-hydroxyTHF] and Au – [alaninol], the hydrogen bonding comprised of Au – ···HO as a strong, primary hydrogen bond, with secondary stabilization by weaker Au – ···HN or Au – ···HC hydrogen bonds. Interestingly, the Au – ···HC bonds in Au – [fenchone] and Au – [menthone] can be characterized as hydrogen bonds, despite their classification as nonconventional hydrogen bond donors.

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