Metal–organic
framework (MOF)-based membranes have been
widely used in gas and liquid separation due to their porous structures
and tunable compositions. Depending on the guest components, heterostructured
MOFs can exhibit multiple functions. In the present work, we report
a facile and rapid preparation of zeolitic imidazolate framework-8
(ZIF-8) and silver nanoparticle incorporated ZIF-8 (Ag/ZIF-8)-based
membranes on stainless-steel mesh (SSM) through a “green”
electrodeposition method. The SSM was first coated with a Zn-plated
layer which contains mainly zinc hydroxide nitrate (Zn5(OH)8(NO3)2·2H2O)
with a “leaf-like” morphology, providing anchoring points
for the deposition of ZIF-8 and Ag/ZIF-8. It takes only 10 min to
prepare a uniform coating of Zn5(OH)8(NO3)2·2H2O in aqueous conditions without
the use of a strong base; this is by far the most efficient way of
making zinc hydroxide nitrate nanocrystals. Following a similar electrodeposition
approach, ZIF-8 and Ag/ZIF-8-coated SSM can be prepared within 20
min by applying a small current. The encapsulation of Ag does not
alter the chemical composition nor the crystal structure of ZIF-8.
The resulting ZIF-8 and Ag/ZIF-8-coated SSM have been tested for their
effectiveness for rhodamine B dye removal in a fast vacuum filtration
setting. Additionally, growth of E. coli was significantly
inhibited after overnight incubation with Ag/ZIF-8-coated SSM. Overall,
we demonstrate a fast synthesis procedure to make ZIF-8 and Ag/ZIF-8-coated
SSM membranes for organic dye removal with excellent antimicrobial
activity.