A review on recent advances in Prussian blue, its analogues, and their derived materials as electrodes for high performance supercapacitors

Kitchamsetti, Narasimharao

doi:10.1016/j.est.2023.108958

Journal of Energy Storage

2023

DOI: 10.1016/j.est.2023.108958

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A review on recent advances in Prussian blue, its analogues, and their derived materials as electrodes for high performance supercapacitors

Narasimharao Kitchamsetti

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2024

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Cited by 21 publications

References 235 publications

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Longevous Protic Hybrid Supercapacitors Using Bimetallic Prussian Blue Analogue/rGO‐Based Nanocomposite Against MXene Anode

Stephanie,

Park,

Hyun

et al. 2024

Small

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MXenes exhibit a unique combination of properties—2D structure, high conductivity, exceptional capacity, and chemical resistance—making them promising candidates for hybrid supercapacitors (HSCs). However, the development of MXene‐based HSCs is often hindered by the limited availability of cathode materials that deliver comparable electrochemical performance, especially in protic electrolytes. In this study, this challenge is addressed by introducing a durable protic HSC utilizing a bimetallic Prussian Blue Analogue (PBA) decorated on reduced graphene oxide (rGO) as a nanocomposite cathode paired with a single‐layered Ti3C2Tx MXene (SL‐MXene) anode. The bimetallic PBA, specifically nickel hexacyanocobaltate (NiHCC), is utilized by virtue of its open and stable structure that facilitates efficient charge storage, leading to enhanced stability and energy storage capabilities. The resulting NiHCC/rGO//SL‐MXene cell demonstrates impressive performance, achieving a maximum specific energy of 38.03 Wh kg−1 and a power density of 20 666.67 W kg−1. Remarkably, the NiHCC/rGO//SL‐MXene HSC cell also exhibits excellent cycling stability without any loss even after 15 000 cycles while retaining ≈100% coulombic efficiency. This work underscores the potential of bimetallic PBA materials with conductive rGO backbone for overcoming the limitations of current MXene‐based protic HSCs, highlighting the significance of this work.

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Longevous Protic Hybrid Supercapacitors Using Bimetallic Prussian Blue Analogue/rGO‐Based Nanocomposite Against MXene Anode

Stephanie,

Park,

Hyun

et al. 2024

Small

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Evaluating polyanthranilic acid as a polymeric template for the production of Prussian blue nanoclusters

Gilpin,

McCormick,

McMath

et al. 2024

J Mater Sci

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The electropolymerization of anthranilic acid (2-aminobenzoic acid) has been shown to lead to the production of a redox polymer functionalized with carboxylate groups capable of complexing metal ions. The polymer was exploited as a means of capturing ferric ion from solution with the iron decorated polymer chains used as seeding points for the formation of Prussian blue (PB). Nanoclusters of PB were dispersed throughout the three-dimensional polymer matrix with deposition achieved through direct electrochemical means or via a dip process. The latter exploited the chemical combination of Fe(III) + Ferrocyanide to yield PB allowing its dispersal of the PB throughout the polymer film. The polymer film and its subsequent modification have been characterized by electron microscopy, X-ray analysis, Raman spectroscopy and electrochemical analysis. The stability toward peroxide has also been explored. Graphical Abstract

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Towards Prussian blue analogues-based advanced aqueous batteries: From facing critical challenges to feasible solutions

Ren,

Xu,

et al. 2024

Coordination Chemistry Reviews

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A review on recent advances in Prussian blue, its analogues, and their derived materials as electrodes for high performance supercapacitors

Cited by 21 publications

References 235 publications

Longevous Protic Hybrid Supercapacitors Using Bimetallic Prussian Blue Analogue/rGO‐Based Nanocomposite Against MXene Anode

Longevous Protic Hybrid Supercapacitors Using Bimetallic Prussian Blue Analogue/rGO‐Based Nanocomposite Against MXene Anode

Evaluating polyanthranilic acid as a polymeric template for the production of Prussian blue nanoclusters

Towards Prussian blue analogues-based advanced aqueous batteries: From facing critical challenges to feasible solutions

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