In coal based thermal power plant, the boiler components (superheater, combustion chamber, superheater tubes, boiler walls, reheater etc.) are subjected to harsh environment characterized by high temperatures, aggressive combustion products, and abrasive particles. Corrosion, erosion, and oxidation relentlessly reduce their lifespan and efficiency, posing significant economic and safety concerns. This review explores the potential of surface modification techniques to act as a valiant shield against these destructive forces, extending the life, enhancing the performance, and ensuring the safe operation of boiler components. In this articles various surface modifications techniques including their merits and demerits are discussed with emphasis on thermal spray techniques. From established methods like thermal spraying and laser cladding to innovative approaches like nanocoatings and electrochemical treatments, each technique is meticulously examined for its effectiveness in boosting corrosion resistance, mitigating erosion wear, and minimizing oxidation at crucial boiler locations. This review culminates in a compelling vision of the future, where sophisticated surface modification techniques become an integral part of boiler design and maintenance strategies. By harnessing the power of these technologies, we can usher in an era of more efficient, reliable, and sustainable boiler operation, safeguarding investments and protecting the environment.