2008
DOI: 10.1002/cssc.200700097
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A Robust Ionic Liquid as Reaction Medium and Efficient Organocatalyst for Carbon Dioxide Fixation

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Cited by 67 publications
(24 citation statements)
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“…Among of all these catalysts, the one with the highest N content (Entry 1 in Table I) presented the highest catalytic activity because N þ was the reactive center of the cycloaddition reaction catalyzed by imidazolebased ILs. 35 Although N content of CLPN with the molar ratio of EGDMA to [VMIm]Cl of 2 : 1 (entry 3 in Table I) was lower than the one of entry 2 in Table I, it still exhibited much higher catalytic activity, which was presumably because the nanoparticles were separated [ Fig. 1(a)] and could be dispersed easily in ECH.…”
Section: Coupling Carbon Dioxide With Epichlorohydrinmentioning
confidence: 90%
“…Among of all these catalysts, the one with the highest N content (Entry 1 in Table I) presented the highest catalytic activity because N þ was the reactive center of the cycloaddition reaction catalyzed by imidazolebased ILs. 35 Although N content of CLPN with the molar ratio of EGDMA to [VMIm]Cl of 2 : 1 (entry 3 in Table I) was lower than the one of entry 2 in Table I, it still exhibited much higher catalytic activity, which was presumably because the nanoparticles were separated [ Fig. 1(a)] and could be dispersed easily in ECH.…”
Section: Coupling Carbon Dioxide With Epichlorohydrinmentioning
confidence: 90%
“…Wong et al have successfully prepared a new ionic liquid that can function both as an organocatalyst and a reaction medium . This ionic liquid (Scheme ) efficiently catalyzed the synthesis of cyclic carbonates with CO 2 and was very robust, allowing constant reuse without showing any significant loss in its catalytic activity.…”
Section: Synthesis Of Nipu By Step‐growth Polyadditionmentioning
confidence: 99%
“…Wong's group designed and synthesized a new IL (D), which showed high catalytic activity for the formation of cyclic carbonates under mild conditions in the presence of small amount of water (Scheme 6) [21]. The IL plays dual roles as an organocatalyst and the reaction medium.…”
Section: Scheme 4 Formation Of Cyclic Carbonates Catalyzed By Recovementioning
confidence: 99%