A sandwich-like heterometallic Fe₇Sn₆ oxo cluster constructed by tessellation of an Anderson-like {Fe₇} wheel for near-infrared photothermal conversion

Abstract

Herein we report a unique sandwich-like heteropolyoxometalate Fe7Sn6, which features an Anderson-type {Fe7} wheel sandwiched by two {Sn3} deckers and is formed via the coordination-induced effect of 2,6-pyridinedicarboxylate. The highly...