The thermochemical
conversion of biomass, through gasification
and consecutive fuel synthesis, can produce high-quality fuels. Entrained-flow
gasification is regarded as the forthcoming technology providing syngas
of sufficient quality, though the technology readiness level needs
to be raised to allow its wide use. To this end, investigations within
the bioliq project have been conducted on the gasification of fast
pyrolysis products: pyrolysis oil and biochar, forming together a
so-called bioslurry. This article will present the parametrization
and results of numerical simulations of entrained-flow gasification.
A first set of simulations on the gasification of a liquid fuel on
two well-referenced experimental data sets is presented. Here, the
liquid is monoethylene glycol, a surrogate for pyrolysis oil. Then,
simulations of slurry fuels are considered, where the conversion of
the biochar particles is numerically solved with a sectional approach.
The simulations prove to retrieve the experimental results with a
high accuracy, thus making CFD simulations based on the proposed approaches
an adapted tool to investigate further operating conditions or for
scaling-up. Particular attention is drawn on the parametrization of
the approach. It will be shown that the majority of the model’s
parameters, such as the pseudospecies size distribution, composition,
and thermodynamic properties, can be derived from regular analytical
chemistry techniques. The parameter with the highest sensitivity was
identified to be the gasification reaction rate of the secondary char.
The proposed model is sensitive to the properties of different types
of biochar as well as to the amount of solid in the slurry fuel. By
presenting a methodology, which can be quickly adapted to further
solid fuels, the present work will allow for tackling the variability
of biomass-derived fuels and find suitable operating conditions adapted
to specific biomass conditions.