A series of boron difluoride complexes of azinylcarbazoles: synthesis and structure–property relationships

Yamamoto, Kōji; Matsui, Susumu; Kato, Shin‐ichiro; Nakamura, Yosuke

doi:10.1039/d3ob00795b

Org. Biomol. Chem.

2023

DOI: 10.1039/d3ob00795b

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A series of boron difluoride complexes of azinylcarbazoles: synthesis and structure–property relationships

Kōji Yamamoto¹,

Susumu Matsui²,

Shin‐ichiro Kato³

et al.

Abstract: A series of boron difluoride (BF2) complexes of azinylcarbazoles 1b–1h were synthesized, and the effects of the structure of azine moieties on the photophysical and electrochemical properties of the BF2...

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Construction of Boron Difluoride Complexes with Asymmetric N,N’‐Bidentate Ligands

Zhao,

Ren,

Zhou

2024

Chemistry A European J

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Boron difluoride (BF2) complexes with asymmetrical N,N’‐bidentate ligands have received increasing attention due to their fascinating properties and broad applications. They are generally constructed in two steps: ligand formation, followed by boron complexation. This review focuses on categorizing these BF2 complexes based on the key synthetic strategies that have been applied in the ligand formation steps. The post‐functionalization, properties and applications of different types of BF2 complexes are presented. Their challenges and opportunities are also discussed. This should help the future rational design and synthesis of BF2 complexes with intriguing properties and practical applications.

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Construction of Boron Difluoride Complexes with Asymmetric N,N’‐Bidentate Ligands

Zhao,

Ren,

Zhou

2024

Chemistry A European J

View full text Add to dashboard Cite

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1-Azaazulene: A Ligand Moiety for Boron Difluoride (BF₂) Complexes To Achieve Long-Wavelength Absorption

Zhao,

Yuan,

Zhou

2024

Org. Lett.

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1-Azaazulene was adopted as a new ligand moiety for boron difluoride (BF 2 ) complexes, resulting in large red shifts of the absorption bands up to 103 nm compared to their isomeric quinoline-based complexes. Such change was attributed to the nonalternant nature of 1-azaazulene, as the complexes maintained the intrinsic 10πperipheral electronic structure. 1a exhibited the most red-shifted absorption among reported BF 2 complexes containing a phenolic backbone, and the absorption edge of 1b reached the red region.

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A series of boron difluoride complexes of azinylcarbazoles: synthesis and structure–property relationships

Abstract: A series of boron difluoride (BF2) complexes of azinylcarbazoles 1b–1h were synthesized, and the effects of the structure of azine moieties on the photophysical and electrochemical properties of the BF2...

Cited by 2 publications

References 30 publications

Construction of Boron Difluoride Complexes with Asymmetric N,N’‐Bidentate Ligands

Construction of Boron Difluoride Complexes with Asymmetric N,N’‐Bidentate Ligands

1-Azaazulene: A Ligand Moiety for Boron Difluoride (BF₂) Complexes To Achieve Long-Wavelength Absorption

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A series of boron difluoride complexes of azinylcarbazoles: synthesis and structure–property relationships

Abstract: A series of boron difluoride (BF2) complexes of azinylcarbazoles 1b–1h were synthesized, and the effects of the structure of azine moieties on the photophysical and electrochemical properties of the BF2...

Cited by 2 publications

References 30 publications

Construction of Boron Difluoride Complexes with Asymmetric N,N’‐Bidentate Ligands

Construction of Boron Difluoride Complexes with Asymmetric N,N’‐Bidentate Ligands

1-Azaazulene: A Ligand Moiety for Boron Difluoride (BF2) Complexes To Achieve Long-Wavelength Absorption

Contact Info

Product

Resources

About

1-Azaazulene: A Ligand Moiety for Boron Difluoride (BF₂) Complexes To Achieve Long-Wavelength Absorption