2019
DOI: 10.1002/slct.201901352
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A Series of Umbrella‐Shape Copper‐Lanthanides Based Mixed Metallic Coordination Complexes

Abstract: A series of six hetero‐bimetallic complexes having umbrella shape topology and general formula (L)2CuLn(NO3)(Ph3PO) have been synthesized by reacting a methanolic solution of diprotic ligand (H2L) [(E)‐2‐(((2‐hydroxyphenyl)imino)methyl)‐6‐methoxyphenol] and co‐ligand Ph3P=O with CuCl2.2H2O and Ln(NO3)3⋅6H2O (Ln= Gd(1), Tb(2),Dy(3), Ho(4), Er(5) and Y(6)) in the presence of triethylamine base. The iso‐structural complexes (1‐6) have been characterized by Single crystal XRD measurement. Elemental analysis, EPR, … Show more

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