A shape-memory poly(ε-caprolactone) hybridized TiO2/poly(l-lactide) composite with antibacterial properties

Hu, Xiaohong; Song, Xiaofeng; Xu, Mengfei; Wang, Yanhe; Zhu, Chuanming; Yu, Wanting; Zhao, Yuze

doi:10.1016/j.ijbiomac.2023.126567

International Journal of Biological Macromolecules

2023

DOI: 10.1016/j.ijbiomac.2023.126567

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A shape-memory poly(ε-caprolactone) hybridized TiO2/poly(l-lactide) composite with antibacterial properties

Xiaohong Hu,

Xiaofeng Song,

Mengfei Xu

et al.

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2024

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Cited by 5 publications

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A Triple Shape Memory Material of Trans‐Polyisoprene/Polycaprolactone with Customizable Response Temperature Controlled by Crosslinking Density

Zhang,

Zou,

Pan

et al. 2024

Adv Funct Materials

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Body‐temperature responsive shape memory polymers (SMPs) attract a lot of attention with the application in biomedicine. Multiple SMPs regulate the response temperature through the proportion of their stationary and reversible phases by changing the molecular weight of the polymer or the components of the composite. Herein, a crosslinking reaction of trans‐polyisoprene (TPI) and polycaprolactone (PCL) initiated by benzoyl peroxide gave a SMP of TPI/PCL, whose shape memory property is realized by stage‐division crystallization zone. Under the fixed ratio of TPI:PCL, the crystallization performance of TPI/PCL is controlled by the crosslinking density. The response temperatures of the components in TPI/PCL are selected for the stage‐division crystallization zone, making excellent shape memory performance at corresponding response temperatures. For the further achievement in controllable response temperature within a certain range, the relationship model between crosslinking density and response temperature is established, obtaining the customizable response temperature ranging 37–55 °C. The presented facile regulation method for response temperature will provide a new idea for the SMPs development.

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A Triple Shape Memory Material of Trans‐Polyisoprene/Polycaprolactone with Customizable Response Temperature Controlled by Crosslinking Density

Zhang,

Zou,

Pan

et al. 2024

Adv Funct Materials

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Facet engineering of α-MnO2 for directly electrocatalytic oxygen atom transfer from water toward epoxidation

Tian,

Li,

Wang

et al. 2024

Chemical Engineering Journal

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The effect of Pluronic P123 on shape memory of cross-linked polyurethane/poly(l-lactide) biocomposite

Chen,

Song,

Wang

et al. 2024

International Journal of Biological Macromolecules

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A shape-memory poly(ε-caprolactone) hybridized TiO2/poly(l-lactide) composite with antibacterial properties

Cited by 5 publications

References 57 publications

A Triple Shape Memory Material of Trans‐Polyisoprene/Polycaprolactone with Customizable Response Temperature Controlled by Crosslinking Density

A Triple Shape Memory Material of Trans‐Polyisoprene/Polycaprolactone with Customizable Response Temperature Controlled by Crosslinking Density

Facet engineering of α-MnO2 for directly electrocatalytic oxygen atom transfer from water toward epoxidation

The effect of Pluronic P123 on shape memory of cross-linked polyurethane/poly(l-lactide) biocomposite

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