Ternary nanocomposites synergistically combine the material
characteristics
of three materials, altering the desired charge storage properties
such as electrical conductivity, redox states, and surface area. Therefore,
to improve the energy synergistic of SnO2, TiO2, and three-dimensional graphene, herein, we report a facile hydrothermal
technique to synthesize a ternary nanocomposite of three-dimensional
graphene–tin oxide–titanium dioxide (3DG–SnO2–TiO2). The synthesized ternary nanocomposite
was characterized using material characterization techniques such
as XRD, Raman spectroscopy, FTIR spectroscopy, FESEM, and EDXS. The
surface area and porosity of the material were studied using Brunauer–Emmett–Teller
(BET) studies. XRD studies showed the crystalline nature of the characteristic
peaks of the individual materials, and FESEM studies revealed the
deposition of SnO2–TiO2 on 3DG. The BET
results show that incorporating 3DG into the SnO2–TiO2 binary nanocomposite increased its surface area compared
to the binary composite. A three-electrode system compared the electrochemical
performances of both the binary and ternary composites as a battery-type
supercapacitor electrode in different molar KOH (1, 3, and 6 M) electrolytes.
It was determined that the ternary nanocomposite electrode in 6 M
KOH delivered a maximum specific capacitance of 232.7 C g–1 at 1 A g–1. An asymmetric supercapacitor (ASC)
was fabricated based on 3DG–SnO2–TiO2 as a positive electrode and commercial activated carbon as
a negative electrode (3DG–SnO2–TiO2//AC). The ASC delivered a maximum energy density of 28.6 Wh kg–1 at a power density of 367.7 W kg–1. Furthermore, the device delivered a superior cycling stability
of ∼97% after 5000 cycles, showing its prospects as a commercial
ASC electrode.