A Silver(I) Coordination Polymer Chain Containing Nanosized Tubes with Anionic and Solvent Molecule Guests

Hong, Maochun; Zhao, Yingjun; Su, Weiping; Cao, Rong; Fujita, Makoto; Zhou, Zhóngyuan; Chan, Albert S. C.

doi:10.1002/1521-3773(20000717)39:14<2468::aid-anie2468>3.0.co;2-i

Cited by 302 publications

(135 citation statements)

References 6 publications

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“…MOFs based on polynuclear metal cluster units are usually built by using polydentate ligands with a variety of coordination modes [17][18][19]. Tripodal carboxylic acid ligands are known to be good for designing MOF materials with varied topologies due to their flexible coordination modes [20][21][22][23], and because the carboxylic acid groups can connect metals to form polynuclear metal cluster units which show excellent magnetic properties [24,25].…”

Section: Introductionmentioning

confidence: 99%

Structure and magnetism of a porous three-dimensional metal-organic framework based on planar tetranuclear copper(II) cluster units

Zhang

Guo

et al. 2010

Sci. China Chem.

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A porous three-dimensional copper(II) metal-organic framework (MOF) {[Cu 2 (tci)(OH)(pip) 0.5 (H 2 O)]·6H 2 O} n (1) [tci = tris (2-carboxyethyl)isocyanurate, pip = piperazine] has been generated under hydrothermal conditions at 120 °C. Single crystal X-ray diffraction reveals that the polymer exhibits a novel three-dimensional framework based on planar tetranuclear copper(II) cluster units. The variable temperature magnetic susceptibility data in the range 2-280 K show antiferromagnetic spin-spin coupling in the tetranuclear unit in complex 1. A theoretical fitting of the magnetic data gives J values of 31.3 cm 1 , 30.8 cm 1 , and 13.5 cm 1 . metal-organic framework, tetranuclear copper cluster unit, topology, magnetism

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Section: Introductionmentioning

confidence: 99%

Structure and magnetism of a porous three-dimensional metal-organic framework based on planar tetranuclear copper(II) cluster units

Zhang

Guo

et al. 2010

Sci. China Chem.

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“…MOFs with d 10 metals have been reported to exhibit interesting fluorescent properties [46,47]. The solid-state luminescent properties of H 2 L and complex 2 were investigated at room temperature and the emission spectra are shown in Fig.…”

Section: Luminescent Propertymentioning

confidence: 85%

Three isostructural 3D supramolecules with p-thioacetatebenzoic acid ligand: syntheses, structure characterizations, and properties

et al. 2010

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p-Thioacetatebenzoic acid (H 2 L) and a combination of N-donor ligand of 4,4 0 -bipyridine (4,4 0 -bipy) with metal(II) ions give rise to three 3D supramolecules of general formula [M(HL) 2 (4,4 0 -bipy) 2 (H 2 O) 2 ] Á H 2 O, M = Co II (1), Zn II (2), Ni II (3), which were characterized by crystallographic methods. The crystals are isostructural and belong to the triclinic P " 1 space group. The structure can be considered to construct from 1D chains and further linked by hydrogen bonds into the final 3D supramolecular networks. The electrochemical behavior of complexes 1 and 3 were studied by cyclic voltammetry, indicating that the electron transfers in the electrode reaction are irreversible. Meanwhile, complex 2 exhibits significantly red-shifted emission in solid state at room temperature.

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“…Numerous complexes with flexible multidentate ligands have been synthesized and studied because the flexibility and conformation freedoms of such ligands offer the possibility for the construction of diverse frameworks with tailored properties and functions [2][3][4]. The 1,3-benzothiazole-2-thiolate (hmbt) is aversatile ligand with more than one donor atom and many of its complexes have been synthesized [5,6].…”

Section: Discussionmentioning

confidence: 99%

Crystal structure of 1-azonia-1-(2-mercaptobenzothiazolyl)ethyl-2- thiolato-1,3-benzothiazole, C16H12N2S4

Guo¹,

Hu²,

Miao³

et al. 2010

Zeitschrift Für Kristallographie - New Crystal Structures

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A Silver(I) Coordination Polymer Chain Containing Nanosized Tubes with Anionic and Solvent Molecule Guests

Cited by 302 publications

References 6 publications

Structure and magnetism of a porous three-dimensional metal-organic framework based on planar tetranuclear copper(II) cluster units

Structure and magnetism of a porous three-dimensional metal-organic framework based on planar tetranuclear copper(II) cluster units

Three isostructural 3D supramolecules with p-thioacetatebenzoic acid ligand: syntheses, structure characterizations, and properties

Crystal structure of 1-azonia-1-(2-mercaptobenzothiazolyl)ethyl-2- thiolato-1,3-benzothiazole, C16H12N2S4

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