A Simple and Efficient Preparation of High‐Purity Hydrogen Trioxide (HOOOH)

Strle, Gregor; Cerkovnik, Janez

doi:10.1002/ange.201504084

Cited by 2 publications

(2 citation statements)

References 29 publications

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“…However, reports about reactions of singlet oxygen with CNTs found in the literature mostly describe different cycloadditions to the CNTs graphitic walls and epoxidations leading to the functionalization of the CNTs, similar to ozone. 89,90 Another possibility is the release of hydrogen trioxide (HOOOH), as it has been shown from trialkylsilane, 88,91 which in turn might give rise to different oxygen radicals like hydroperoxyl (HOO • ) and hydroxyl (OH • ) radicals.…”

Section: Chemistry Of Materialsmentioning

confidence: 99%

Atomic Layer Deposition of Silica on Carbon Nanotubes

et al. 2017

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Low-temperature ozone-assisted atomic layer deposition (ALD) of SiO2 with four silane derivatives (3-aminopropyl)triethoxysilane (APTES), bis(diethylamino)silane (BDEAS), diphenylaminosilane (DPAS), and triethylsilane on carbon nanotubes (CNTs) leads to the one step formation of SiO2 nanotubes. In the process, CNTs act as templates and are removed during the ongoing deposition. From transmission electron microscopy images, the formation of a void between the CNTs surface and the SiO2 coating was observed, indicating an unexpected removal of carbon from the CNTs. This gap grows as the number of ALD cycles is increased, eventually leading to SiO2 nanotubes almost free of carbon. ATR-IR and EELS spectra proved the SiO2 formation. Depending on the CNTs templates used in this process, different morphologies of one-dimensional SiO2 nanostructures are obtained, including simple nanotubes, hollow wall nanotubes, tube-in-tube structures, and SiO2 nanowires. The application of this process on vertically aligned CNTs (VACNTs) templates allows the formation of a perfect SiO2 replica of the VACNTs. From experiments with different oxygen and silicon precursors, it is proposed that peroxides and oxygen-based radicals, which can be formed from the reaction of surface Si–H species with ozone, are the main reactive species leading to the unexpected etching of carbon from the CNTs during silica ALD.

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Section: Chemistry Of Materialsmentioning

confidence: 99%

Atomic Layer Deposition of Silica on Carbon Nanotubes

et al. 2017

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“…On the PES, the global and local minima, transition states were revealed as well as the characteristics of НТ were compared with those of hydroxide peroxide [26]. The investigations of the PES were continued in the papers [27][28][29], while the mechanisms [30] and enthalpies [31,32] of the formation of the HT molecule and methods of its synthesis [33,34] were determined by quantumchemical methods in a number of papers.…”

Section: Introductionmentioning

confidence: 99%

The torsional spectrum of the hydrogen trioxide molecule

2020

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The energies of the stationary torsional levels of the hydrogen trioxide molecule were calculated at the B3LYP, MP2, and CCSD(T) levels of theory using augmented correlation consistent acc-pVTZ basis set. The molecular symmetry group whose elements are inherent to both equilibrium conformer's symmetry elements (C2 and CS) of the HT molecule was found.Different methods of the molecular parameters calculations were suggested and analyzed. The torsional, spin and total wave functions were classified by irreducible representations of the C2V(M) molecular symmetry group. The 2D dipole moment surface was calculated too. The energies of the stationary torsional states were found using DVR and Fourier methods. With this and acceptable combinations of spatial and spin wave functions, the IR torsional spectrum was calculated at different temperatures. The tunneling frequencies in the ground and some excited torsional states were estimated too.

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A Simple and Efficient Preparation of High‐Purity Hydrogen Trioxide (HOOOH)

Cited by 2 publications

References 29 publications

Atomic Layer Deposition of Silica on Carbon Nanotubes

Atomic Layer Deposition of Silica on Carbon Nanotubes

The torsional spectrum of the hydrogen trioxide molecule

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