Networks based on IEEE 802.11 standard are one of the main options for deployment in industrial environment. Degradation of throughput in congested networks and short-term unfairness are well-known drawbacks of 802.11 DCF and similar MAC protocols. Those shortcomings represent significant limitation in forecasted growth of wireless usage. This is especially important in industrial wireless networks (IWN) where the scalability of wireless MAC is one of the main requirements. In this paper, a novel self-adapting MAC protocol (SaMAC) is defined and mathematically modeled. SaMAC employs constrained countdown freezing enhanced with shifted window mechanism. As a result, the protocol outperforms 802.11 DCF standard as well as shifted contention window (SCW) and constrained countdown freezing (CPCF) protocols in achieved throughput, fairness, and jitter, while keeping simple implementation. Despite protocol’s simple design, it is shown that its mathematical model is extremely complex. For proposed protocol, the assumption of constant contention loss probability, which is normally used for modeling of MAC schemes, does not hold. In the presented multidimensional Markov chain model, a unique iterative method for determining contention loss probability is developed as well as a method for throughput calculation based on such a chain. Accuracy of the presented model is verified in several network scenarios. Considering the performance of the proposed protocol, authors believe that it could be of benefit to deploy it in heavily loaded wireless networks with timing constraints, such as IWNs.