The surface properties (water sorption and repellency, adhesion) are closely related to the surface tension of polymer solid. Critical surface tension c C and surface tension c S of a polymer solid have been estimated by the contact angle method by our quantitative imaging system. BPDA (3,3 0 ,4,4 0 -biphenyl tetracarboxylic dianhydride) -EDA (4,4 0 -ethylenedianiline) polyimide was successfully synthesized. The critical surface tensions c C were analyzed by a Zisman plot, a Young-Dupre´-Good-Girifalco plot, and a log (1 þ cos h) vs log c L plot. The surface tension c S of BPDA-EDA polyimide was evaluated using the geometric mean equation and our multiple regression analysis. The calculated values of c d S (a dispersion component), c p S (a polar component), c h S (a hydrogen bonding component), and c S are 30.49, 4.52, 0.08, and 35.09 mN Á m À1 , respectively. The c S of BPDA-EDA polyimide containing two methylene groups is smaller than those of the polyimides containing both methylene group and ether group.