A Simpler Route for Making Nitrogen-Alkene Rings

Türkmen, Yunus E.; Aggarwal, Varinder K.

doi:10.1126/science.1248166

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Cited by 7 publications

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Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp³)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Wang

Liu

et al. 2019

Adv Synth Catal

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A Rh(III)‐catalyzed intermolecular unactivated secondary C(sp3)−H bond amidation via nitrene insertion directed by 3,5‐dimethylpyrazole is reported. This procedure tolerates a broad substrate scope including chain and cyclic N‐alklyamides. Notably, the directing group 3,5‐dimethylpyrazole of chain N‐alkylamide substrates could be easily removed via cascade intermolecular amidation and intramolecular cyclization in one‐pot affording the sulfonylureas by increasing the reaction temperature.

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Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp³)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Wang

Liu

et al. 2019

Adv Synth Catal

View full text Add to dashboard Cite

show abstract

Reusable and Removable Directing Groups for C(sp²)−H Bond Functionalization of Arenes

et al. 2015

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Ruthenium-Catalyzed C−N and C−O Bond-Forming Processes from C−H Bond Functionalization

Dana

Yadav

Sahoo

2015

C-H Bond Activation and Catalytic Functionalization I

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A Simpler Route for Making Nitrogen-Alkene Rings

Abstract: A common nitrogen building block used in many natural product and drug syntheses can now be made in its unprotected form in a single step.

Cited by 7 publications

References 9 publications

Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp³)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp³)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Reusable and Removable Directing Groups for C(sp²)−H Bond Functionalization of Arenes

Ruthenium-Catalyzed C−N and C−O Bond-Forming Processes from C−H Bond Functionalization

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A Simpler Route for Making Nitrogen-Alkene Rings

Abstract: A common nitrogen building block used in many natural product and drug syntheses can now be made in its unprotected form in a single step.

Cited by 7 publications

References 9 publications

Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp3)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp3)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Reusable and Removable Directing Groups for C(sp2)−H Bond Functionalization of Arenes

Ruthenium-Catalyzed C−N and C−O Bond-Forming Processes from C−H Bond Functionalization

Contact Info

Product

Resources

About

Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp³)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Rhodium(III)‐catalyzed Intermolecular Unactivated Secondary C(sp³)−H Bond Amidation Directed by 3,5‐dimethylpyrazole

Reusable and Removable Directing Groups for C(sp²)−H Bond Functionalization of Arenes