With the growing desire for new buildings and better indoor comfort, the amount of energy consumption of office buildings in China is increasing rapidly, which will lead to the great challenge for energy supply and sustainable development. Building passive envelop energy efficient measures (PEEEMs), mainly including exterior wall insulation, roof insulation, different glazing types, and shading system, were widely applied. However, the specific energy efficient performance of PEEEMs was various in different climate conditions that have not been evaluated clearly yet. The priority order of PEEEMs was not recommended in relative standards. The economic benefits cannot be considered synchronously with PEEEMs optimization. This paper modified the sensitivity analysis to fit the building energy efficiency evaluation. By combining the modified method with a simulation tool, the energy efficiency and economic effects of PEEEMs of office buildings in various climate regions can be considered at the same time. Four case buildings in Shenyang, Tianjin, Ningbo, and Shenzhen were proved to reach the energy-saving potentials of 9.44%, 7.75%, 20.87%, and 13.27% respectively, with the payback period of no more than 1.5 years. Finally, the recommended application priority rankings and the recommended ranges of thermal performance properties of PEEEMs in the four typical climate regions were presented.