The cathodoluminescence (CL) technique is frequently used to study semiconductor materials. The quantitative determination of material parameters requires an accurate simulation of the CL signal as a function of electron beam parameters (i.e. intensity I p , energy E 0 ). The free surface of a semiconductor can be described by a defect density N t , which induces localised electron states E t in the band gap. The surface is generally charged, which induces a band bending near the surface. Hence, a potential barrier E b is formed across a space-charge region. The electric field E in this region causes the carriers to drift towards the surface and enhances their recombination. This latter is treated using the Shockley-Read-Hall theory. This paper deals with the case of n-GaAs, particularly the comparison between the numerical results of the model and experimental data obtained from the literature. A connection between the movement of the energy levels E t considered in this model and the surface recombination velocity V s is established.