The Radiance Enhancement (RE) method was introduced for efficient detection of clouds from the space. Recently we have also reported that due to high reflectance of combustion-originated smokes this approach can also be generalized for detection of the forest fires by retrieving and analyzing datasets collected from a space orbiting micro-spectrometer operating in the near infrared spectral range. In our previous publication we have performed a comparison of observed and synthetic radiance spectra by developing a method for computation of surface reflectance consisting of different canopies by weighted sum based on their areal coverage. However, this approach should be justified by a method based on corresponding proportions of the upwelling radiance. The results of computations we performed in this study reveals a good match between areal coverage of canopies and the corresponding proportions of the upwelling radiance due to effect of the instrument slit function.