With the prosperity and development of the Maritime Silk Road, China's maritime industry has reached a new height. While the maritime transport industry has been vigorously developed, it has also brought great challenges to safe navigation. To realize intelligent navigation, effectively prevent maritime collision accidents, and improve navigation safety, a structural model of intelligent navigation obstacle avoidance platform based on Internet of Things technology is first proposed. Then the research combines the analytic hierarchy process, artificial neural network and BP neural network algorithm, and introduces environmental factors to design an optimized intelligent navigation obstacle avoidance algorithm, so that the algorithm can make real-time intelligent adjustment strategies according to the changes of the actual environment. Finally, the collision risk at the location of the research ship is judged, and the priority list of obstacle avoidance is constructed by the risk value between different ships and the research ship, providing reference for the pilot. The research results show that the prediction accuracy of I-INOA algorithm is 97.83%. In the two obstacle avoidance experiments, the decision-making efficiency of the four ships based on I-IONA algorithm is the highest, which is 1. In practical application, the priority list of obstacle avoidance is P, O and S2. In conclusion, I-INOA algorithm has better performance and practicability, enabling the research ship to respond more intelligently and quickly.