A stable enolate complex from tetramethyl-3-thietanone and diiron nonacarbonyl: .mu.-O-.mu.-S-(2,4-dimethyl-4-thiolato-2-penten-3-olato)diiron hexacarbonyl

Czauderna, Bernhard; Jogun, Kurt H.; Stezowski, John J.; Foehlisch, B.

doi:10.1021/ja00437a044

Cited by 15 publications

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“…Tetramethyl-3-thietanone was reported to form stable complexes with diiron nonacarbonyl . Thietan-3-ones were also obtained by decomposition of another diiron nonacarbonyl complex.…”

Section: A2 Synthesis By Ring Transformationsmentioning

confidence: 99%

“…232 Tetramethyl-3-thietanone was reported to form stable complexes with diiron nonacarbonyl. 233 Thi-etan-3-ones were also obtained by decomposition of another diiron nonacarbonyl complex. The complex formed by 2-tert-butyl-3-(diphenylmethylene)thiirane and diiron nonacarbonyl decomposed when heated in toluene in a sealed tube to give rise to the corresponding alkylidenethietan-3-one with a yield of 45%.…”

Section: A2 Synthesis By Ring Transformationsmentioning

confidence: 99%

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The Chemistry of Azetidin-3-ones, Oxetan-3-ones, and Thietan-3-ones

et al. 2001

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I. Introduction 29 II. The Chemistry of Azetidin-3-ones 29 A. Structural Data 29 B. Synthetic Methods for Azetidin-3-ones 31 B.1. Carbonyl Group Generation in the Azetidine Ring 31 B.2. Intramolecular Cyclization Reactions 34 B.3. 1,3-Dipolar Cycloaddition Reactions 36 C. Chemical Properties of Azetidin-3-ones 37 C.1. Transformations of the Carbonyl Group 37 C.2. Condensation Reactions − Synthesis of 2-Benzylideneazetidin-3-ones 40 C.3. Ring Transformations of Azetidin-3-ones 40 C.4. Miscellaneous 41 III. The Chemistry of Oxetan-3-ones 42 A. Structural Data 42 B. Synthetic Methods for Oxetan-3-ones 43 B.1. Decomposition of Diazoketones 43 B.2. Oxidation Reactions 44 B.3. Intramolecular Displacement Reactions 46 B.4. Miscellaneous 47 C. Chemical Properties of Oxetan-3-ones 48 C.1. Ring Opening and Ring Expansion of Oxetan-3-ones 48 C.2. Transformations of the Carbonyl Group 49 IV. The Chemistry of Thietan-3-ones 50 A. Synthetic Methods for Thietan-3-ones 51 A.1. Synthesis from Acyclic Precursors 51 A.2. Synthesis by Ring Transformations 53 B. Chemical Properties of Thietan-3-ones 54 B.1. Transformations of the Carbonyl Group 55 B.2. Aldol Reactions 56 B.3. Ring Transformations 56 V. Acknowledgments 58 VI. References 58

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“…Tetramethyl-3-thietanone was reported to form stable complexes with diiron nonacarbonyl . Thietan-3-ones were also obtained by decomposition of another diiron nonacarbonyl complex.…”

Section: A2 Synthesis By Ring Transformationsmentioning

confidence: 99%

Section: A2 Synthesis By Ring Transformationsmentioning

confidence: 99%