The B − L MSSM is the MSSM with three right-handed neutrino chiral multiplets and gauged B − L symmetry. The B − L symmetry is broken by the third family right-handed sneutrino acquiring a VEV, thus spontaneously breaking R-parity. Within a natural range of soft supersymmetry breaking parameters, it is shown that a large and uncorrelated number of initial values satisfy all present phenomenological constraints; including the correct masses for the W ± , Z 0 bosons, having all sparticles exceeding their present lower bounds and giving the experimentally measured value for the Higgs boson. For this "valid" set of initial values, there are a number of different LSPs, each occurring a calculable number of times. We plot this statistically and determine that among the most prevalent LSPs are chargino and neutralino mass eigenstates. In this paper, the R-parity violating decay channels of charginos and neutralinos to standard model particles are determined, and the interaction vertices and decay rates computed analytically. These results are valid for any chargino and neutralino, regardless of whether or not they are the LSP. For chargino and neutralino LSPs, we will-in a subsequent series of papers -present a numerical study of their RPV decays evaluated statistically over the range of associated valid initial points. B Mass Matrix elements 54 B.1 Chargino mass matrix 54 B.2 Neutralino mass matrix 55 -1 --4 -In Section 2, we give a brief summary of the B − L MSSM. In particular, the spontaneous breaking of gauged U (1) B−L symmetry by a non-vanishing VEV of the third family right-handed sneutrino is discussed. The associated R-parity violating interactions induced in the Lagrangian are presented in detail. The VEV of the right-handed sneutrino produces a mixing of the third family right-hand neutrino and the three left-handed neutrinos with all fermionic superpartners of the neutral gauge bosons and the up and down neutral Higgsinos. This is presented in Section 3. The general form of this 9 × 9 mass matrix is given, as well as the explicit form of the unitary matrix required to diagonalize it. However, in that section, we focus on the diagonal 3 × 3 left-handed neutrino Majorana submatix m D ν only. The mass eigenvalues of this matrix can be determined from the explicit form of the PMNS mixing matrix as well as the off-diagonal lefthanded neutrino matrix m ν . This latter matrix is a function of the R-parity violating parameters as well as three additional quantities. The result is compared with the experimentally determined mass eigenvalues of both the "normal" and the "inverted" neutrino mass hierarchies. In Section 4, we list all of the presently known experimental data that must be satisfied in any phenomenologically acceptable vacuum. These include the masses of the W ± ,Z 0 electroweak vector bosons, the Higgs mass, the present lower bounds on the SUSY sparticles and so on. Having done this, we present the mass interval in which we will statistically throw all dimensionful parameters of the soft SUSY breaking t...