Over the past several years, parton distribution functions (PDFs) have become more precise. However there are still kinematic regions where more data are needed to help constrain global PDF extractions, such as the sea quark distributionsd/ū near the valence region (Bjorken-x ≈ 0.1 -0.3). Current measurements appear to suggest different high-x behaviors of these distributions, leading to large uncertainties in global fits. The charged W cross section ratio (W + /W − ) is sensitive to the unpolarized u, d,ū, andd quark distributions at large Q 2 set by the W mass and could help shed light on this discrepancy. The STAR experiment at RHIC is well equipped to measure the leptonic decays of W bosons, in the mid-rapidity range (|η| ≤ 1), produced in proton+proton collisions at √ s = 500/510 GeV. At these kinematics STAR is sensitive to quark distributions nearBjorken-x of 0.16. STAR can also measure the W cross section ratio in a more forward bin ranging from 1