1979
DOI: 10.1080/00268977900101531
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A stochastic theory of non-ideal behaviour

Abstract: The stochastic theory described in Part I is extended here to the case of a ternary system [A, B, C] at equilibrium. Using the microenvironment and the quasi-chemical (QC) approximations, we derive equations to estimate the differences in chemical potentials in terms of the three pair interaction parameters O)AB , mAC and OgBc. Alternative equations for calculating these differences have been derived by Bell, using the QC approximation alone. We show that, within the framework of the QC approximation, these es… Show more

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Cited by 7 publications
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References 27 publications
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