Alumina, or aluminum oxide, has several applications as Biomaterial in addition to being used in machining tools, grinding, thermal insulation, shielding, refractory for heating furnaces, electrical insulators, electronic components due to its high resistance to high temperatures, hardness, mechanical resistance and chemical resistance. Its achievement is due to intermediate processes in the manufacture of primary aluminum, as well as physical and chemical deposition processes. This work aims to obtain thin films of alumina through the Plasma Electrolytic Oxidation process, using the 5052 aluminum alloy as a substrate. This study serves as a basis for applications of thin films of alumina in Implantable Centrifugal Blood Pump rotors used as Ventricular Assist Devices developed by the Laboratory of Bioengineering and Biomaterials in the Federal Institute of São Paulo. The samples were prepared with same surface area of the rotor, in order to simulate the same behavior of the rotor film deposition, thus being able to observe the morphology at different oxidation times and energies, and how the influence of time and energy on the generation of plasma micro-arcs act in the formation of the alumina film. The film was characterized with Scanning Electron Microscopy, Dispersive Energy Spectroscopy and X-Ray Diffraction. The ceramic films in the PEO are created by the reaction of the electrolytic solution with the electrical discharges produced by a source, being deposited on the surface of the samples through micro arcs. In the future, the films will be tested for cell viability, and will also be evaluated as an internal coating of Implantable Centrifugal Blood Pump for use as Ventricular Assist Device.