The symplectic Brill-Noether locus S k 2n,K associated to a curve C parametrises stable rank 2n bundles over C with at least k sections and which carry a nondegenerate skewsymmetric bilinear form with values in the canonical bundle. This is a symmetric determinantal variety whose tangent spaces are defined by a symmetrised Petri map. We obtain upper bounds on the dimensions of various components of S k 2n,K . We show the nonemptiness of several S k 2n,K , and in most of these cases also the existence of a component which is generically smooth and of the expected dimension. As an application, for certain values of n and k we exhibit components of excess dimension of the standard Brill-Noether locus B k 2n,2n(g−1) over any curve of genus g ≥ 122. We obtain similar results for moduli spaces of coherent systems.2010 Mathematics Subject Classification. 14H60 (14M12).