In this paper we report the effective atomic number (Z eff ) of some rare earth compounds determined from the measured external bremsstrahlung (EB) intensity due to the incident beta particles emitted by the 90 Sr-90 Y source. For this purpose the two sample method evolved recently by the authors was employed. A high purity germanium detector was used in the present study to improve the resolution of the detection system. The constants lnK, n, C and D for the present geometry and the detector were determined by using the EB intensity measured for the elemental foils Al, Cu, Ag, Sn and Pb of varying thickness. The Z eff values obtained were in good agreement with the Z mod values given by the theoretical expression of Markowicz and Van Grieken. Possible conclusions are drawn based on the present study.