Ethanol is a renewable alternative fuel in many application areas. The external electric field is applied to assist the small ethanol diffusion flame in this study. The electrical response of flame under the uniform electric field is discussed. A reduced chemical mechanism of ethanol is used to establish a numerical model corresponding to the experimental system. The characteristics of current-electric field strength, equivalent resistance, distribution of charged species, velocity field, and reaction rate are studied. The results show that the electric field brings significant effects on the combustion and electrical characteristics of flame. As the electric field strength increases, the current through the circuit and the equivalent resistance of the flame show a three-stage variation. The current increases first (0-40 kV/m), then stabilizes (40-70 kV/m) and then continues to increase (70-100 kV/m) with the increase of the electric field