“…MOFs based on porphyrin-metal complexes can selectively absorb small molecules, such as CO 2 , CO, and CH 4 , et al [23], to activate these small molecules in catalysis, especially, selectively absorb CO 2 [24], and realize its catalytic electroreduction. Film of tetra(4-carboxyphenyl)porphyrin Fe complex-Zr-O cluster possessed high face concentration, and as catalysts for electroreduction from CO 2 to CO, the overpotential was efficiently reduced [25].…”