A study of the hydration of ions

Solvation numbers of ions

“…i v i d u a l n o t d i r e c t l y a s s o c i a t e d w i t h s c i t e i s p r o h i b i t e d .water 543. The data do not bear out the observations644•645 that a relaxation peak existed at35 Me. This brought into question assignment of relaxation peaks to the steps in the…”

“…The formula of the ions from water was H2+(«/.>0(e/<>+. The Coulombic interaction energies between these ions and cations and anions are, respectively Ek = -nkee/Rk (35) and Ea = naee/Rk (36) where /?k and R" are the distances between the charges of water ions in the tint coordination spheres and the centers (191) O. Ya.…”

Solvation of Ions

“…It was observed [35] through the hydration of ions derived from the transport of water that Kohlrausch's law of independent migration of ions does not hold exactly in fairly concentrated solutions. It was also found that for concentrated solutions electroosmotic transport does not interfere with electrolytic transport in the determination of hydration.…”