The emulsified feedstock technique
derived from micro-explosion
has been applied to improve the feedstock atomization of heavy oil
during the catalytic cracking process. The strength of an interfacial
film, which is vital for the stability of emulsion, can be enhanced
by some polymer surfactants. In this study, n-hexadecane
was chosen as the model oil. The effect of oil–water interfacial
film properties on the high-temperature breakup of emulsified droplets
was investigated, especially the interfacial film strength of water-in-oil
(W/O) emulsion in the presence of a commonly used non-ionic surfactant
and/or polymer surfactant (Arlacel-P135). The mean diameter of dispersed
water and interfacial tension and interfacial film strength of emulsions
were measured. Afterward, two breakup modes of emulsified droplets
were revealed by the single droplet heating test, which are “micro-explosion”
and “breakup after bubble expansion”. The emulsified
droplet stabilized by Arlacel-P135 is more prone to “breakup
after bubble expansion” for the rigid oil–water interfacial
film hindering the coalescence of dispersed water. The stability and
oil–water interfacial strength of emulsions stabilized by mixed
surfactants consisting of Span80, Tween80, and Arlacel-P135 were enhanced
with the increase in Arlacel-P135 dosage. Moreover, the addition of
Arlacel-P135 (0.2–0.5 wt %) significantly reduced the average
breakup delay time (τ) of W/O droplets, since the bubble nucleation
was favored by the interfacial film structure formed by polymer surfactant.