A Study of the Products Obtained by the Reducing Action of Metals upon Salts in Liquid Ammonia Solutions. VII. The Reduction of Complex Nickel Cyanides: Mono-valent Nickel

Eastes, John W.; Burgess, Wayland M.

doi:10.1021/ja01257a053

Cited by 67 publications

(9 citation statements)

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“…All chemicals and solvents used in this study were of analytical grade and used as received except K 3 [Cu(CN) 4 ] which was prepared by the method described in the literature [40]. Elemental analysis was performed with a Perkin Elmer 2400 automatic elemental analyzer, while copper was determined using a Perkin Elmer 2380 atomic absorption spectrometer.…”

Section: Materials and General Methodsmentioning

confidence: 99%

Double Stranded Helical Organo-lead 3D-Supramolecular Coordination Polymer Containing Copper Cyanide and Phenanthroline Ligand as Antimicrobial Agent

Etaiw

Abdou

2015

J Inorg Organomet Polym

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The supramolecular coordination polymer (SCP) [Cu(CN) 2 (Me 3 Pb)phen]; 1 is formed by selfassembly of K 3 [Cu(CN) 4 ], Me 3 PbCl and 1,10-phenanthroline (phen) ligand at ambient conditions. The copper center is coordinated to two ordered cyanide ligands and two nitrogen atoms of the phen ligand forming distorted tetrahedral configuration. The structure of 1 consists of repeating units of the tetrahedral Cu(phen)(CN) 2 fragments connected by the (Me 3 Pb) ? cations forming1-D helical chains. The 1-D helical chains are arranged in a unique way to construct a right-helical and a left-helical chain creating a double-helical 3-D network arranged in a unique AÁÁÁAÁÁÁA fashion. H-bonds and p-p stacking play an important role in stabilizing the structure of 1. IR, 1 H-NMR, electronic and luminescence spectra as well as thermal analysis are also investigated. The SCP 1 has high antimicrobial activity against E. coli and S. aureus and it also exhibits good activity against the fungal strains, C. albicans and A. Niger. The results of growth inhibiting effect indicated that the inhibitory effect is increased with an increase in concentration of the SCP 1.

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Section: Materials and General Methodsmentioning

confidence: 99%

Double Stranded Helical Organo-lead 3D-Supramolecular Coordination Polymer Containing Copper Cyanide and Phenanthroline Ligand as Antimicrobial Agent

Etaiw

Abdou

2015

J Inorg Organomet Polym

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“…All chemicals and solvents used in this study were of analytical grade supplied by Aldrich or Merck and used as received except K 3 [Cu(CN) 4 ], which was prepared in the laboratory according to literature [35]. Microanalyses (C, H, N) were carried out with a Perkin Elmer 2400 automatic elemental analyzer.…”

Section: Methodsmentioning

confidence: 99%

In vitro and in vivo antitumor activity of novel 3D-organotin supramolecular coordination polymers based on CuCN and pyridine bases

Etaiw

Sultan

El‐bendary

2011

Journal of Organometallic Chemistry

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“…K 3 [Cu(CN) 4 ] was prepared following the literature procedure [22]. Organotin chlorides which are mainly, trimethyltin chloride and triphenyltin chloride as well as qaz were purchased from Aldrich, Sigma and Fluka and used without further purification.…”

Section: Methodsmentioning

confidence: 99%

New Organotin/CuCN/Quinazoline 3D-Supramolecular Coordination Polymers Having Catalytic and Luminescence Activities

Etaiw

Abdou

2011

J Inorg Organomet Polym

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The new bimetallic supramolecular coordination polymers (SCP); 3 ∞ [Cu(CN) 2 ·Me 3 Sn·qaz], 1 and 3 ∞ [Cu 2 (CN) 4 ·(Ph 3 Sn) 2 ·qaz], 2 (qaz = quinazoline), are prepared in water/acetonitrile solvent at room temperature. The structure of 1 consists of the anionic Cu(CN) 2 building blocks connected by the Me 3 Sn cations to form zigzag chains which are bridged by qaz creating 2D-sheets. The interwoven infinite sheets are arranged in parallel A···A···A fashion developing 3D-network structure via H-bonds, π-π stacking, and Cu-C contacts. The network structure of 2 exhibits two different copper sites forming two Cu(CN) 2 building blocks which are connected by the Ph 3 Sn groups constructing elongated corrugated chains. The qaz ligand connects these chains forming 3D-network structure containing the rhombic [Cu 2 (μ 3 -CN) 2 ] motif. 1 and 2 are luminescent materials which can be used in applications as molecular sensing systems. Also, the catalytic activity of 1 and 2 was investigated towards the degradation of Metanil Yellow (MY) dye by dilute solution of hydrogen peroxide as oxidant.

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A Study of the Products Obtained by the Reducing Action of Metals upon Salts in Liquid Ammonia Solutions. VII. The Reduction of Complex Nickel Cyanides: Mono-valent Nickel

Cited by 67 publications

References 0 publications

Double Stranded Helical Organo-lead 3D-Supramolecular Coordination Polymer Containing Copper Cyanide and Phenanthroline Ligand as Antimicrobial Agent

Double Stranded Helical Organo-lead 3D-Supramolecular Coordination Polymer Containing Copper Cyanide and Phenanthroline Ligand as Antimicrobial Agent

In vitro and in vivo antitumor activity of novel 3D-organotin supramolecular coordination polymers based on CuCN and pyridine bases

New Organotin/CuCN/Quinazoline 3D-Supramolecular Coordination Polymers Having Catalytic and Luminescence Activities

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