A Study of the Properties of the System Lithium Chlorate-Water. I. Introduction. Ii. Phase Relations

Abstract

The oxide so prepared is shown to contain 10.87% of oxygen as compared with the calculated percentage, 10.85, of oxygen in auric oxide. Qualitative evidence is also adduced to show that the product is pure within the limits of experimental error.

A Thermoanalytical Study of Lithium Chlorate.

“…The polymorphism of LiClOs has been a matter of some dispute in the literature. Some workers (29) have claimed the reversible crystallographic changes • ±ß, &^±a at 44.5°and 106.4°, respectively, whereas others (3, 10) have reported but a single crystallographic transition at about 100°. Accordingly, in the present study, DTA patterns of LiClOs on an expanded scale were obtained over the temperature range from ambient to about 180°.…”

Physical Properties of cis-1-Cyano-1,3-butadiene

“…Anhydrous LÍ2SO4 was prepared from J. T. Baker reagent LÍ2CO3 which had been recrystallized by the method of Kraus and Burgess. 14 The final product was heated in platinum in a muffle furnace at 550-600°to remove the last traces of acid and water.…”

The Electrochemistry of Molten Lithium Chlorate and Its Possible Use with Lithium in a Battery

“…Using this process the "dried" lithium chlorate melted between 126 ~ and 128~ According to the chlorate-water phase diagram proposed by Krauss et al (8), a melting point of lithium chlorate between 126 ~ and 128~ corresponds to a water content of less than 0.5%. Lithium chlorate is known to be extremely hygroscopic (8). As long as the water content in the lithium chlorate was 0.5% or less, no gross effects associated with water were observed.…”