“…Commercial value of TBV changes a lot with age and special prices are requested for very old vinegar (25 years old or older). Several authors have attempted to solve the problem focusing their efforts on analytical studies (Chiavaro, Caligiani, & Palla, 1988;Plessi, Monzani, & Coppini, 1989;Giudici, 1993;Giudici, Barbagallo, Altieri, & Masini, 1994;Zeppa, Giordano, Gerbi, & Meglioli, 2002;Masino, Chinnici, Franchini, Ulrici, & Antonelli, 2005;Muratore, Licciardello, Restuccia, Puglisi, & Giudici, 2006), chemiometric characterization (Consonni & Gatti, 2004;Cocchi, Bro et al, 2006;Durante, Cocchi, Grandi, Marchetti, & Bro, 2006); and physical measurements (Falcone, Chillo, Giudici, & Del Nobile, 2007). Unfortunately, the results have been very far from proving the vinegar authenticity or differentiating among vinegars of different ages.…”