Joining of Ti and Fe-based alloys is challenging due to the formation of deleterious phases at the interface. Since fusion welding is unsuitable for the purpose, over the years, many solid-state welding techniques have been tried. This review provides a comparison of different solid-state joining methods used for Fe/Ti alloys with focus on the structural transformations in base materials, effect of process parameters on interface microstructure, its evolution and kinetics with thermal aging and structure–property correlation. Structural transformations in diffusion couples (near-equilibrium condition) are compared with those in weldments and a perspective is provided on the role of defects and alloying additions in enhancing/retarding reaction zone formation under both equilibrium and non-equilibrium conditions.