The identification of risks associated with collision for vessels is an important element in maritime safety and management. A vessel collision avoidance system is a topic that has been deeply studied, and it is a specialization in navigation technology. The automatic identification system (AIS) has been used to support navigation, route estimation, collision prediction, and abnormal traffic detection. This article examined the main elements of ship collision, developed a mathematical model for the risk assessment, and simulated a collision assessment based on AIS information, thereby providing meaningful recommendations for crew training and a warning system, in conjunction with the AIS on board.