Early prevention methods in massive concrete structures to control the heat of hydration and, consequently, the development of cracks due to thermal expansion are important subjects, since these cracks may compromise structural integrity. In the present study, the sugarcane residues in massive concrete were used in order to investigate the reduction in the heat of hydration, the thermal expansion resistance, and also the fresh and mechanical properties of the concrete. The results showed that, by adding 2.0% of bagasse fiber and 5.0% of pozzolanic material to the concrete, the heat of hydration was reduced, and the strain due to the thermal expansion was smaller than the control mixture. Moreover, the compressive, flexural, and split tensile strength increased in comparison to the control mixture.