This study was carried out to develop a selective sequential precipitation process for recovering dissolved metals from acid mine drainages (AMD). The AMD of pH 3 with high concentration of Fe, Al and Mn at the Samma-Teajung coal mine was neutralized by adding neutralizing agents and oxidant to evaluate recovery of the metals and purity of their precipitates. In the case of adding only neutralizing agents, both dissolved Al and Mn were concurrently precipitated at pH 4.5 so that caused the purity of each precipitate to be lowered. However, for neutralization preceded by oxidation of AMD, dissolved metals were removed sequentially in the order of Fe, Al and Mn. Recoveries of dissolved Fe, Al and Mn reached 99.2∼99.3% at pH 4.5, 70.4∼82.2% at pH 5.5, and 37.8∼87.5% at pH 8.5, respectively. Oxidation before neutralization increased the recovery of dissolved Fe and Al in AMD with high purity of precipitates.