A Study on the Development of CVD Precursors VI-Thermal Properties of Co(III) β-Diketonates

“…Complexes 1-5 were synthesized using reported methods 49 with minor changes. 32 50 213 °C, 49 220 °C, 219-220 °C, 30 220 °C51 ); IR ῡ (cm −1 ): 1580 (CO); 30,52 NMR (600 MHz, CDCl 3 , 25 °C): δ 6.07 (s, 1H, CH), 6.05 (s, 1H, CH), 6.01 (s, 1H, CH), 2.45 (s, 3H, CH 3 ), 2.44 (s, 3H, CH 3 ), 2.40 (s, 3H, CH 3 ); 13 C NMR (150 MHz, CDCl 3 , 25 °C): δ 199.5 (CO), 199.0 (CO), 198.9 (CO), 170.8 (q, J C-F = 34.6 Hz, CO), 170.6 (q, J C-F = 34.8 Hz, CO), 170.1 (q, J C-F = 34.7 Hz, CO), 114.4 (q, J C-F = 282.7 Hz, CF 3 ), 94 (CH), 94.1 (CH),94.3 (CH), (CH 3 ), 27.7 (CH 3 ), 27.5 (CH 3 ); 19…”

Section: Synthesismentioning

confidence: 99%

Spectroscopic and DFT study of tris(β-diketonato)cobalt(III) complexes

Twigge

Conradie

Erasmus

2023

Journal of Chemical Research

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Nuclear magnetic resonance measurements confirm that, as expected, the mer isomer of tris(β-diketonato) cobalt(III) complexes is more stable ( mer isomers are more stable because they are less affected by steric hindrance and they have lower dipoles). An excess of the mer isomer or only the mer isomer is experimentally observed. The existence of both fac and mer isomers is predicted by density functional theory calculations. At room temperature, the nuclear magnetic resonance peaks of phenyl-containing mer complexes are broad due to the intermediate rotation of bulky phenyl groups resulting in only the average orientation of the non-equivalent protons in the mer complexes. However, upon heating to 55 °C (thus speeding up the rotation) or cooling to −50 °C (slowing down the rotation), this broad peak is resolved into three sets of carbon peaks appearing in the 13C NMR spectrum, as well as splitting of the 1H NMR peaks for the non-equivalent protons in the mer isomer. In solid-state 13C NMR the aromatic rings do not rotate, resulting in the splitting of all the 13C NMR peaks. Two sets of well-defined peaks are observed for the fluorine-containing compound [Co(CF3COCHCOCPh)3] in both the 13C and 19F NMR spectra, indicating that both the fac and mer isomers are present with a ratio of fac:mer = 0.1:1. The X-ray photoelectron spectroscopy measured binding energy of the Co 2p3/2 photoelectron lines are influenced by the subtle electronic (electron-donating or electron-withdrawing) properties of the R groups on the β-diketonato ligands. Various relationships are established between the binding energy of Co 2p3/2 and several physical and density functional theory–calculated properties, confirming good electronic communication (the measurable electronic effect that a molecular fragment has on the physical properties of another molecular fragment in the molecule) of the substituent groups through the pseudo aromatic system of the β-diketonato backbones to the metal.

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