Polytetrafluoroethylene (PTFE) was discovered by chance in 1938 by Roy Plunkett at the DuPont company, and within a decade establishment of initial commercial production facilities brought PTFE's widespread availability. In addition to this polymer's high melting point and chemical resistance, its unusually low friction behavior was noted early on, 1 leading to a great deal of activity over the half-century since developing a basic understanding of its tribological capabilities as well as its useful application as a self-lubricating bearing material. This chapter surveys the molecular and crystalline structure of PTFE and its related transfer film and friction behavior, the severe wear mechanism often accompanying such transfer behavior and its prevention via hard micro-fillers within a PTFE composite, as well as alternate approaches towards wear resistance which avoid the abrasive countersurface damage such hard filler particles also typically present. Finally, the recent development of extremely wear-resistant PTFE nano-composites is presented.
Processing and StructurePTFE, -(CF 2 -CF 2 ) n -, is polymerized into a powder form from tetrafluoroethylene gas 2 under pressure in an aqueous medium via a free radical-initiated addition process to extremely high molecular weight chains of up to M n >10 8 . This polymerization creates linear chains of smooth profile, lacking branches or bulky side groups. As opposed to the planar zigzag of the carbon backbone of polyethylene chains, where each CH 2 group has effectively rotated 180 o from its neighbor, the carbon Polymer Tribology Downloaded from www.worldscientific.com by KAINAN UNIVERSITY on 02/20/15. For personal use only.