“…For the case of tellurite filling, such reactions may involve diffusion of tellurite species into the silica matrix, dissolution of silica in the tellurite melt, interfacial crystallization and phase separation. Secondly, process-induced volume reactions may occur such as increasing fictive pressure [3,4], the generation of structural anisotropy as a result of shear-flow [5,6], isotropic changes in network topology as a result of the applied body forces [7], solution and re-boiling of gases [8,9], or pressure and confinementdependent crystallization or phase separation processes [10]. In a first consideration, especially the interfacial reactions would lead to the occurrence of scattering centers inside the waveguide and, hence, to very high optical loss.…”