The traditional knowledge service systems have nonuniform data structures. Some data are structured, while some are semi-structured and even non-structured. Big data technology helps to optimize the integration and retrieval of the massive data on library and information (L&I), making it possible to classify the resources and optimize the configuration of L&I resource platforms according to user demand. Therefore, this paper introduces the new information service model of big data resources and knowledge services to the processing of L&I data. Firstly, the data storage structure and relationship model of the L&I resource platform were established, and used to sample and integrate the keywords of resource retrieval. Next, an L&I resource classification model was constructed based on support vector machine (SVM), and applied to extract and quantify the attributes of the keywords of resource retrieval. After that, a knowledge aggregation model was developed for a complex network of multiple L&I resource platforms. Experimental results demonstrate the effectiveness of the proposed knowledge aggregation model. The research findings provide a reference for the application of data mining in resource classification.